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PROTOCOL OF 1978 RELATING TO THE INTERNATIONAL CONVENTION FOR THEREVENTION OF POLLUTION FROM SHIPS, 197

PROTOCOL OF 1978 RELATING TO THE INTERNATIONAL CONVENTION FOR THEREVENTION OF POLLUTION FROM SHIPS, 197 Whole document Regulation 10 Surveys (1) Ships carrying noxious liquid substances in bulk shall be subject to the surveys specified below: (a) An initial survey before the ship is put in service or before the certificate required under regulation 11 of this Annex is issued for the first time, and which shall include a complete survey of its structure, equipment, systems, fittings, arrangements and material in so far as the ship is covered by this Annex. This survey shall be such as to ensure that the structure, equipment, systems, fittings, arrangements and material fully comply with the applicable requirements of this Annex.

(b) Periodical surveys at intervals specified by the Administration, but not exceeding five years, and which shall be such as to ensure that the structure, equipment, systems, fittings, arrangements and material fully comply with the requirements of this Annex.

(c) A minimum of one intermediate survey during the period of validity of the certificate and which shall be such as to ensure that the equipment and associated pump and piping systems fully comply with the applicable requirements of this Annex and are in good working order. In cases where only one such intermediate survey is carried out in any one certificate validity period, it shall be held not before six months prior to, nor later than six months after the half-way date of the certificate's period of validity. Such intermediate surveys shall be endorsed on the certificate issued under regulation 11 of this Annex.

(d) An annual survey within three months before or after the day and the month of the date of issue of the certificate and which shall include a general examination to ensure that the structure, fittings, arrangements and materials remain in all respects satisfactory for the service for which the ship is intended. Such annual surveys shall be endorsed on the certificate issued under regulation 11 of this Annex.

(2) (a) Surveys of ships as regards the enforcement of the provisions of this Annex shall be carried out by officers of the Administration. The Administration may, however, entrust the surveys either to surveyors nominated for the purpose or to organizations recognized by it.

(b) An Administration nominating surveyors or recognizing organizations to conduct surveys and inspections as set forth in subparagraph (a) of this paragraph, shall as a minimum empower any nominated surveyor or recognized organization to: (i) require repairs to a ship; and (ii) carry out surveys and inspections if requested by the appropriate authorities of a port State.

the Administration shall notify the Organization of the specific responsibilities and conditions of the authority delegated to the nominated surveyors or recognized organizations, for circulation to Parties to the present Convention for the information of their officers.

(c) When a nominated surveyor or recognized organization determines that the condition of the ship or its equipment does not correspond substantially with the particulars of the certificate, or is such that the ship is not fit to proceed to sea without presenting an unreasonable threat of harm to the marine environment, such surveyor or organization shall immediately ensure that corrective action is taken and shall in due course notify the Administration. If such corrective action is not taken the certificate should be withdrawn and the Administration shall be notified immediately; and if the ship is in a port of another Party, the appropriate authorities of the port State shall also be notified immediately. When an officer of the Administration, a nominated surveyor or recognized organization has notified the appropriate authorities of the port State, the Government of the port State concerned shall give such officer, surveyor, or organization any necessary assistance to carry out their obligations under this regulation. When applicable, the Government of the port State concerned shall take such steps as will ensure that the ship shall not sail until it can proceed to sea or leave the port for the purpose of proceeding to the nearest appropriate repair yard available without presenting an unreasonable threat of harm to the marine environment.

(d) In every case, the Administration concerned shall fully guarantee the completeness and efficiency of the survey and inspection and shall undertake to ensure the necessary arrangements to satisfy this obligation.

(3) (a) The condition of the ship and its equipment shall be maintained to conform with the provisions of the present Convention to ensure that the ship in all respects will remain fit to proceed to sea without presenting an unreasonable threat of harm to the marine environment.

(b) After any survey of the ship under paragraph (1) of this regulation has been completed, no change shall be made in the structure, equipment, systems, fittings, arrangements or material covered by the survey, without the sanction of the Administration, except the direct replacement of such equipment and fittings.

(c) Whenever an accident occurs to a ship or a defect is discovered which substantially affects the integrity of the ship or the efficiency or completeness of its equipment covered by this Annex, the master or owner of the ship shall report at the earliest opportunity to the Administration, the recognized organization or the nominated surveyor responsible for issuing the relevant certificate, who shall cause investigations to be initiated to determine whether a survey as required by paragraph (1) of this regulation is necessary. If the ship is in a port of another Party, the master or owner shall also report immediately to the appropriate authorities of the port State and the nominated surveyor or recognized organization shall ascertain that such report has been made.

Regulation 11 Issue of certificate (1) An International Pollution Prevention Certificate for the Carriage of Noxious Liquid Substances in Bulk shall be issued, after survey in accordance with the provisions of regulation 10 of this Annex, to any ship carrying noxious liquid substances in bulk and which is engaged in voyages to ports or terminals under the jurisdiction of other Parties to the Convention.

(2) Such certificate shall be issued either by the Administration or by any person or organization duly authorized by it. In every case, the Administration assumes full responsibility for the certificate.

(3) (a) The Government of a Party to the Convention may, at the request of the Administration, cause a ship to be surveyed and, if satisfied that the provisions of this Annex are complied with, shall issue or authorize the issue of an International Pollution Prevention Certificate for the Carriage of Noxious Liquid Substances in Bulk to the ship in accordance with this Annex.

(b) A copy of the certificate and a copy of the survey report shall be transmitted as soon as possible to the requesting Administration.

(c) A certificate so issued shall contain a statement to the effect that it has been issued at the request of the Administration and it shall have the same force and receive the same recognition as the certificate issued under paragraph (1) of this regulation.

(d) No International Pollution Prevention Certificate for the Carriage of Noxious Liquid Substances in Bulk shall be issued to a ship which is entitled to fly the flag of a State which is not a Party.

(4) The International Pollution Prevention Certificate for the Carriage of Noxious Liquid Substances in Bulk shall be drawn up in an official language of the issuing country in the form corresponding to the model given in appendix V to this Annex. If the language used is neither English nor French, the text shall include a translation into one of these languages.

Regulation 12 Duration of certificate (1) An International Pollution Prevention Certificate for the Carriage of Noxious Liquid Substances in Bulk shall be issued for a period specified by the Administration, which shall not exceed five years from the date of issue.

(2) A certificate shall cease to be valid if significant alterations have taken place in the construction, equipment, systems, fittings, arrangements or material required without the sanction of the Administration, except the direct replacement of such equipment or fittings, or if intermediate or annual surveys as specified by the Administration under regulation 10 (1) (c) or (d) of this Annex are not carried out.

(3) A certificate issued to a ship shall also cease to be valid upon transfer of the ship to the flag of another State. A new certificate shall be issued only when the Government issuing the new certificate is fully satisfied that the ship is in full compliance with the requirements of regulation 10 (3) (a) and (b) of this Annex. In the case of a transfer between Parties, if requested within three months after the transfer has taken place, the Government of the Party whose flag the ship was formerly entitled to fly shall transmit as soon as possible to the Administration a copy of the certificate carried by the ship before the transfer and, if available, a copy of the relevant survey report.

Regulation 12A Survey and certification of chemical tankers Notwithstanding the provisions of regulations 10, 11 and 12 of this Annex, chemical tankers which have been surveyed and certified by States Parties to the present Convention in accordance with the provisions of the International Bulk Chemical Code or the Bulk Chemical Code, as applicable, shall be deemed to have complied with the provisions of the said regulations, and the certificate issued under that Code shall have the same force and receive the same recognition as the certificate issued under regulation 11 of this Annex.

Regulation 13 Requirements for minimizing accidental pollution (1) The design, construction, equipment and operation of ships carrying noxious liquid substances of Category A, B or C in bulk, shall be such as to minimize the uncontrolled discharge into the sea of such substances.

(2) Chemical tankers constructed on or after 1 July 1986 shall comply with the requirements of the International Bulk Chemical Code.

(3) Chemical tankers constructed before 1 July 1986 shall comply with the following requirements: (a) The following chemical tankers shall comply with the requirements of the Bulk Chemical code as applicable to ships referred to in 1.7.2 of that Code: (i) ships for which the building contract is placed on or after 2 November 1973 and which are engaged on voyages to ports or terminals under the jurisdiction of other States Parties to the Convention; and (ii) ships constructed on or after 1 July 1983 which are engaged solely on voyages between ports or terminals within the State the flag of which the ship is entitled to fly.

(b) The following chemical tankers shall comply with the requirements of the Bulk Chemical Code as applicable to ships referred to in 1.7.3 of that Code: (i) ships for which the building contract is placed before 2 November 1973 and which are engaged on voyages to ports or terminals under the jurisdiction of other States Parties to the Convention; and (ii) ships constructed before 1 July 1983 which are engaged on voyages between ports or terminals within the State the flag of which the ship is entitled to fly, except that for ships of less than 1600 tons gross tonnage compliance with the Code in respect of construction and equipment shall take effect not later than 1 July 1994.

(4) In respect of ships other than chemical tankers carrying noxious liquid substances of Category A, B or C in bulk, the Administration shall establish appropriate measures based on the Guidelines developed by the Organization in order to ensure that the provisions of paragraph (1) of this regulation are complied with.

Regulation 14 Carriage and discharge of oil-like substances Notwithstanding the provisions of other regulations of this Annex, noxious liquid substances designated in Appendix II of this Annex as falling under Category C or D and identified by the Organization as oil-like substances under the criteria developed by the Organization, may be carried on an oil tanker as defined in Annex I of the Convention and discharged in accordance with the provisions of Annex I of the present Convention, provided that all of the following conditions are complied with: (a) the ship complies with the provisions of Annex I of the present Convention as applicable to product carriers as defined in that Annex; (b) the ship carries an International Oil Pollution Prevention Certificate and its Supplement B and the certificate is endorsed to indicate that the ship may carry oil-like substances in conformity with this regulation and the endorsement includes a list of oil-like substances the ship is allowed to carry; (c) in the case of Category C substances the ship complies with the ship type 3 damage stability requirements of: (i) the International Bulk Chemical code in the case of a ship constructed on or after 1 July 1986; or (ii) the Bulk Chemical Code, as applicable under regulation 13 of this Annex, in the case of a ship constructed before 1 July 1986; and (d) the oil content meter in the oil discharge monitoring and control system of the ship is approved by the Administration for use in monitoring the oil-like substances to be carried.

Appendices to Annex II of MARPOL 73/78
Appendix I Guidelines for the categorization of noxious liquidsubstances Category A Substances which are bioaccumulated and liable to produce a hazard to aquatic life or human health, or which are highly toxic to aquatic life (as expressed by a Hazard Rating 4, defined by a TLm less than 1 ppm); and additionally certain substances which are moderately toxic to aquatic life (as expressed by a Hazard Rating 3, defined by a TLm of 1 ppm or more, but less than 10 ppm) when particular weight is given to additional factors in the hazard profile or to special characteristics of the substance.

Category B Substances which are bioaccumulated with a short retention of the order of one week or less, or which are liable to produce tainting of the sea food, or which are moderately toxic to aquatic life (as expressed by a Hazard Rating 3, defined by a TLm of 1 ppm or more, but less than 10 ppm); and additionally certain substances which are slightly toxic to aquatic life (as expressed by a Hazard Rating 2, defined by a TLm of 10 ppm or more, but less than 100 ppm) when particular weight is given to additional factors in the hazard profile or to special characteristics of the substance.

Category C Substances which are slightly toxic to aquatic life (as expressed by a Hazard Rating 2, defined by a TLm of 10 ppm or more, but less than 100 ppm); and additionally certain substances which are practically non-toxic to aquatic life (as expressed by a Hazard Rating 1, defined by a TLm of 100 ppm or more, but less than 1,000 ppm) when particular weight is given to additional factors in the hazard profile or to special characteristics of the substance.

Category D Substances which are practically non-toxic to aquatic life (as expressed by a Hazard Rating 1, defined by a TLm of 100 ppm or more, but less than 1,000 ppm); or causing deposits blanketing the sea floor with a high biochemical oxygen demand (BOD); or which are highly hazardous to human health, with an LD of less than 5 mg/kg; or which produce 50 moderate reduction of amenities because of persistency, smell or poisonous or irritant characteristics, possibly interfering with use of beaches; or which are moderately hazardous to human health, with an LD 50 of 5 mg/kg or more, but less than 50 mg/kg, and produce slight reduction of amenities.

Other Liquid Substances (for the purposes of regulation 4 of this Annex) Substances other than those categorized in Categories A, B, C, and D above.

Appendix II List of noxious liquid substances carried in bulk* [* Pollution Category in brackets indicates that the substance has been provisionally included in this list and that further data are necessary in order to complete the evaluation of its environmental hazards, particularly in relation to living resources. Until the hazard evaluation is completed the Pollution Category assigned shall be used.] |----------------------- | | Pollution | | | category for | Residual concentration | | operational | (% by weight) | UN | discharge | | no. |-----|-------- | Substance | (Reg.3 | (Reg.5 (1) | (Reg.5 (7) | | of Annex II) | of Annex II) | of Annex II) |---|-----|----|----- | I | II | III | IV | | Outside | Within | | special areas | special areas |---------|---|-----|----|----- |---------|---|-----|----|----- | Acetaldehyde | 1089 | C | | Acetic acid | 2789 | D | | Acetic anhydride | D | | Acetone cyanohydrin | 1541 | A | 0.1 | 0.05 | Acrylamide solution | 2074 | D | | (50% or less) | | | Acrylic acid | 2218 | D | | Acrylonitrile | 1093 | B | | Adiponitrile | 2205 | D | | Alcohol (C - C ) poly (1-3) | A | 0.1 | 0.05 | 12 15 | | | ethoxylates | | | Alcohol (C - C ) poly (3-11) | A | 0.1 | 0.05 | 12 15 | | | ethoxylates | | | Alcohol (c - C ) (secondary) | A | 0.1 | 0.05 | 6 17 | | | poly (3-6) ethoxylates | | | Alcohol (c -C ) (secondary) | B | | 6 17 | | | poly (7-12) ethoxylates | | | Alkyl acrylate/Vinylpyridine | C | | copolymer in toluene | | | Alkyl (C - C ) benzenes | (D) | | 9 17 | | | Alkyl benzene sulphonic acid | 2584,| C | | 2586 | | | Alkyl benzene sulphonic acid, | C | | sodium salt solution | | |---------------------- |--------------- | Substance | I | II |III|IV |---------|---|---|--|- | Allyl alcohol | 1098 | B | | Allyl chloride | 1100 | B | | Aluminium chloride | D | | (30% or less) /Hydrochloric acid | | | (20% or less) solution | | | Aluminium sulphate solution | D | | 2- (2-Aminoethoxy) ethanol | 3055 | D | | Aminoethylethanolamine | (D) | | N-Aminoethylpiperazine | 2815 | D | | 2-Amino-2-methyl-1-propanol | D | | (90% or less) | | | Ammonia aqueous | 2672*| C | | (28% or less) | | | Ammonium nitrate solution | D | | (93% or less) | | | Ammonium sulphate solution | D | | Ammonium sulphide solution | 2683 | B | | (45% or less) | | | Ammonium thiocyanate | (C) | | (25% or less) /Ammonium | | | thiosulphate | | | (20% or less) | | | solution | | | Ammonium thiosulphate solution | (C) | | (60% or less) | | | n-Amyl acetate | 1104 | C | | sec-Amyl acetate | 1104 | C | | Amyl acetate, commercial | 1104 | C | | n-Amyl alcohol | 1105 | D | | sec-Amyl alcohol | 1105 | D | | Amyl alcohol, primary | 1105 | D | | Aniline | 1547 | C | | Animal and fish oils, n.o.s. | D | | including: | | | Cod liver oil | | | Sperm oil | | | Aviation alkylates (C paraffins | (C) | | 8 | | | and iso-paraffins | | | BPT 95-120¡æ) | | | Benzene and mixtures having |1114**| C | | 10% benzene or more | | |--------------- [* UN no. refers to 10-35%.] [** UN no. 1114 applies to benzene.] |----------------- | Substance | I | II | III | IV |----------|---|---|---|--- | Benzenesulphonyl chloride | 2225 | D | | Benzyl acetate | C | | Benzyl alcohol | C | | Benzyl chloride | 1738 | B | | Brake fluid base mix: | D | | (Poly (2-8) alkylene (C - C ) | | | 2 3 | | | glycols/Polyalkylene (C - C ) | | | 2 10 | | | glycols/Monoalkyl (C - C )ethers | | | 1 4 | | | and their borate esters) | | | Butene oligomer | B | | n-Butyl acetate | 1123 | C | | sec-Butyl acetate | 1123 | D | | n-Butyl acrylate | 2348 | B | | Butylamine (all isomers) | C | | Butylbenzenes (all isomers) | 2709 | (A) | 0.1 | 0.05 | Butyl benzyl phthalate | A | 0.1 | 0.05 | n-Butyl butyrate | (C) | | Butyl/Decyl/Ceryl/Eicosyl | D | | methacrylate mixture | | | Butylene glycol | D | | 1, 2-Butyl ene oxide | 3022 | C | | n-Butyl ether | 1149 | C | | Butyl lactate | D | | Butyl methacrylate | D | | n-Butyraldehyde | 1129 | B | | Butyric acid | 2820 | D | | gamma-Butyrolactone | D | | Calcium alkyl salicylate | C | | Calcium hydroxide slurry | D | | Calcium hypochlorite solution | C | | (15% or less) | | | Calcium hypochlorite solution | B | | (more than 15%) | | | Calcium naphthenate in | A | 0.1 | 0.05 | mineral oil | | | Camphor oil | 1130 | B | | epsilon-Caprolactam | D | | (molten or aqueous solutions) | | |----------------- |---------------- | Substance | I | II | III | IV |---------|---|---|---|--- | Carbolic oil | A | 0.1 | 0.05 | Carbon disulphide | 1131 | B | | Carbon tetrachloride | 1846 | B | | Cashew nut shell oil | D | | (untreated) | | | Chlorinated paraffins | A | 0.1 | 0.05 | (C - C ) | | | 10 13 | | | Chloroacetic acid | 1750 | C | | (80% or less) | | | Chlorobenzene | 1134 | B | | Chloroform | 1888 | B | | Chlorohydrins (crude) | (D) | | o-Chloronitrobenzene | 1578 | B | | 2-or 3-Chloropropionic acid | (C) | | Chlorosulphonic acid | 1754 | C | | m-Chlorotoluene | 2238 | B | | o-Chlorotoluene | 2238 | A | 0.1 | 0.05 | p-Chlorotoluene | 2238 | B | | Chlorotoluenes | 2238 | A | 0.1 | 0.05 | (mixed isomers) | | | Choline chloride solutions | D | | Citric acid | D | | Coal tar | A | 0.1 | 0.05 | Coal tar naphtha solvent | B | | Coal tar pitch (molten) | D | | Cobalt naphthenate in | A | 0.1 | 0.05 | solvent naphtha | | | Coconut oil fatty acid | C | | Coconut oil fatty acid | D | | methyl ester | | | Creosote (coal tar) | A | 0.1 | 0.05 | Creosote (wood) | A | 0.1 | 0.05 | Cresols (all isomers) | 2076 | A | 0.1 | 0.05 | Cresylic acid | A | 0.1 | 0.05 | sodium salt solution | | | Crotonaldehyde | 1143 | B | | Cycloheptane | 2241 | (C) | |---------------- |---------------- | Substance | I | II | III | IV |---------|---|---|---|--- | Cyclohexane | 1145 | C | | Cyclohexanol | C | | Cyclohexanone | 1915 | D | | Cyclohexyl acetate | (B) | | Cyclohexylamine | 2357 | C | | 1, 3-Cyclopentadiene dimer | B | | (molten) | | | Cyclopentane | 1146 | (C) | | Cyclopentene | (B) | | p-Cymene | 2046 | C | | Decahydronaphthalene | 1147 | (D) | | Decanoic acid | C | | Decene | B | | Decyl acrylate | A | 0.1 | 0.05 | Decyl alcohol (all isomers) | B | | Decylbenzene | D | | Diacetone alcohol | 1148 | D | | Dialkyl (C - C ) phthalates | D | | 7 13 | | | Dibutylamine | C | | Dibutyl phthalate | A | 0.1 | 0.05 | Dichlorobenzenes (all isomers) | 1592 | B | | 1, 1-Dichloroethane | 2362 | B | | Dichloroethyl ether | 1916 | B | | 1, 6-Dichlorohexane | B | | 2, 2'-Dichloroisopropyl ether | 2490 | C | | Dichloromethane | 1593 | D | | 2, 4-Dichlorophenol | 2021 | A | 0.1 | 0.05 | 2, 4-Dichlorophenoxyacetic | A | 0.1 | 0.05 | acid, diethanolamine salt | | | solution | | | 2, 4-Dichlorophenoxyacetic | A | 0.1 | 0.05 | acid, dimethylamine salt | | | solution (70% or less) | | | 2, 4-Dichlorophenoxyacetic | A | 0.1 | 0.05 | acid, triisopropanolamine salt | | | solution | | | 1, 1-Dichloropropane | B | |---------------- |---------------- | Substance | I | II | III | IV |---------|---|---|---|--- | 1, 2-Dichloropropane | 1279 | B | | 1, 3-Dichloropropane | B | | 1, 3-Dichloropropene | 2047 | B | | Dichloropropene/ | B | | Dichloropropane mixtures | | | 2, 2-Dichloropropionic acid | D | | Diethylamine | 1154 | C | | Diethylaminoethanol | 2686 | C | | Diethylbenzene | 2049 | C | | Diethylene glycol butyl ether | (D) | | acetate | | | Diethylene glycol dibutyl | D | | ether | | | Diethylene glycol ethyl ether | (D) | | acetate | | | Diethylene glycol methyl ether | C | | Diethylene glycol methyl | (D) | | ether acetate | | | Diethylenetriamine | 2079 | D | | Di- (2-ethylhexyl) adipate | D | | Di- (2-ethylhexyl) phosphoric | 1902 | C | | acid | | | Diethyl phthalate | C | | Diethyl sulphate | 1594 | (B) | | Diglycidyl ether of | B | | bisphenol A | | | Diglycidyl ether of | B | | bisphenol F | | | Di-n-hexyl adipate | B | | 1, 4-Dihydro-9, 10-dihydroxy | D | | anthracene, disodium salt | | | solution | | | Diisobutylamine | 2361 | (C) | | Diisobutylene | 2050 | B | | Diisobutyl ketone | 1157 | D | | Diisobutyl phthalate | B | | Diisodecyl phthalate | D | |---------------- |---------------- | Substance | I | II | III | IV |---------|---|---|---|--- | Diisononyl adipate | D | | Diisopropanolamine | C | | Diisopropylamine | 1158 | C | | Diisopropylbenzene | A | 0.1 | 0.05 | (all isomers) | | | Diisopropyl naphthalene | D | | N, N-Dimethylacetamide | D | | solution (40% or less) | | | Dimethyl adipate | B | | Dimethylamine solution | 1160 | C | | (45% or less) | | | Dimethylamine solution | 1160 | C | | (greater than 45% but not | | | greater than 55%) | | | Dimethylamine solution | 1160 | C | | (greater than 55% but not | | | greater than 65%) | | | N, N-Dimethylcyclohexylamine | 2264 | C | | Dimethylethanolamine | 2051 | D | | Dimethylformamide | 2265 | D | | Dimethyl glutarate | C | | Dimethyl octanoic acid | (C) | | Dimethyl phthalate | C | | 2, 2-Dimethylpropane-1, 3-diol | (D) | | Dimethyl succinate | C | | Dinitrotoluene (molten) | 1600 | B | | Dinonyl phthalate | D | | 1, 4-Dioxane | 1165 | D | | Dipentene | 2052 | C | | Diphenyl | A | 0.1 | 0.05 | Diphenyl/Diphenyl ether | A | 0.1 | 0.05 | mixtures | | | Diphenyl ether | A | 0.1 | 0.05 | Diphenyl ether/Diphenyl | A | 0.1 | 0.05 | phenyl ether mixture | | | Diphenylmthane diisocyanate | 2489 | (B) | | Diphenylol propane-epichloro | B | |---------------- |---------------- | Substance | I | II | III | IV |---------|---|---|---|--- | hydrin resins | | | Di-n-propylamine | 2383 | C | | Dipropylene glycol methyl | (D) | | ether | | | Ditridecyl phthalate | D | | Diundecyl phthalate | D | | Dodecene (all isomers) | (B) | | Dodecenyl succinic acid, | (D) | | dipotassium salt solution | | | Dodecyl alcohol | B | | Dodecyl diphenyl ether | B | | disulphonate solution | | | Dodecyl phenol | A | 0.1 | 0.05 | Drilling brines, containing | (A) | 0.1 | 0.05 | zinc salts | | | Epichlorohydrin | 2023 | C | | Ethanolamine | 2491 | D | | 2-Ethoxyethanol | 1171 | D | | 2-Ethoxyethyl acetate | 1172 | C | | Ethyl acetate | 1173 | D | | Ethyl acetoactetate | (D) | | Ethyl acrylate | 1917 | A | 0.1 | 0.05 | Ethylamine | 1036 | (C) | | Ethylamine solutions | 2270 | (C) | | (72% or less) | | | Ethyl amyl ketone | 2271 | C | | Ethylbenzene | 1175 | C | | N-Ethylbutylamine | (C) | | Ethyl butyrate | 1180 | C | | Ethylcyclohexane | (C) | | N-Ethylcyclohexylamine | D | | Ethylene chlorohydrin | 1135 | C | | Ethylene cyanohydrin | (D) | | Ethylenediamine | 1604 | C | | Ethylenediamine, tetraacetic | D | | acid, tetrasodium salt solution | | | Ethylene dibromide | 1605 | B | |---------------- |---------------- | Substance | I | II | III | IV |---------|---|---|---|--- | Ethylene dichloride | 1184 | B | | Ethylene glycol | D | | Ethylene glycol acetate | (D) | | Ethylene glycol butyl | (C) | | ether acetate | | | Ethylene glycol diacetate | C | | Ethylene glycol isopropyl ether | D | | Ethyl glycol methyl butyl | D | | ether | | | Ethylene glycol methyl ether | 1188 | D | | Ethylene glycol methyl ether | 1189 | D | | acetate | | | Ethylene glycol phenyl ether | D | | Ethylene glycol phenyl ether/ | D | | Diethylene glycol phenyl | | | ether mixture | | | Ethylene oxide/Propylene | 2983 | D | | oxide mixture with an ethylene | | | oxide contene of not more than | | | 30% in weight | | | 2-Ethylhexanoic acid | D | | 2-Ethylhexyl acrylate | B | | 2-Ethylhexylamine | 2276 | B | | Ethylidene norbornene | B | | Ethyl methacrylate | 2277 | (D) | | o-Ethylphenol | (A) | 0.1 | 0.05 | Ethyl propionate | 1195 | D | | 2-Ethyl-3-propylacrolein | (B) | | Ethyltoluene | (B) | | Ferric chloride solutions | 2582 | C | | Ferric hydroxyethyl | D | | ethylenediamine triacetic acid, | | | trisodium salt solution | | | Ferric nitrate/Nitric acid | C | | solution | | | Formaldehyde solutions | 1198,| C | | (45% or less) | 2209 | | |---------------- |---------------- | Substance | I | II | III | IV |----------|---|---|---|-- | Formamide | D | | Formic acid | 1779 | D | | Fumaric adduct of rosin, | B | | water dispersion | | | Furfural | 1199 | C | | Furfuryl alcohol | 2874 | C | | Glutaraldehyde solutions | D | | (50% or less) | | | Glycidyl ester of C | B | | 10 | | | trialkylacetic acid | | | Glyoxal solution | D | | (40% or less) | | | Heptane (all isomers) | 1206 | (C) | | n-Heptanoic acid | (D) | | Heptanol (all isomers) | C | | Heptene (all isomers) | C | | Heptyl acetate | (B) | | Hexamethylenediamine | D | | adipate (50% in water) | | | Hexamethylenediamine | 1783 | C | | solution | | | Hexamethyleneimine | 2493 | C | | Hexamethylenetetramine | D | | solutions | | | Hexane (all isomers) | 1208 | (C) | | Hexanoic acid | D | | Hexanol | 2282 | D | | Hexene (all isomers) | (C) | | Hexyl acetate | 1233 | B | | Hydrochloric acid | 1789 | D | | Hydrogen peroxide solutions | 2014,| C | | (over 8% but not over 60%) | 2984 | | | Hydrogen peroxide solutions | 2015 | C | | (over 60% but not over 70%) | | | 2-Hydroxyethylacrylate | B | | N- (Hrdroxyethy) ethylene | D | | diamine triacetic acid, trisodium | | |---------------- |-------------- | Substance | I | II | III | IV |---------|---|---|---|--- | salt solution | | | lsoamyl acetate | 1104 | C | | lsoamyl alcohol | 1105 | D | | lsobutyl acetate | 1213 | C | | lsobutyl acrylate | 2527 | B | | lsobutyl formate | 2393 | D | | lsobutyraldehyde | 2045 | C | | lsophorone | D | | lsophoronediamine | 2289 | D | | lsophorone diisocyanate | 2290 | B | | lsoprene | 1218 | C | | lsopropanolamine | C | | lsopropylamine | 1221 | C | | lsopropylbenzene | 1918 | B | | lsopropylcyclohexane | (C) | | lsopropyl ether | 1159 | D | | lsovaleraldehyde | 2058 | C | | Lactic acid | D | | Lactonitrile solution | B | | (80% or less) | | | Latex (ammonia inhibited) | D | | Lauric acid | B | | Maleic anhydride | 2215 | D | | Mercaptobenzothiazol, | B | | sodium salt solution | | | Mesityl oxide | 1229 | D | | Metam sodium solution | A | 0.1 | 0.05 | Methacrylic acid | 2531 | D | | Methacrylic resin in | B | | 1, 2-dichloroethane solution | | | Methacrylonitrile | 3079 | (B) | | 3-Methoxybutyl acetate | 2708 | D | | Methyl acetoacetate | D | | Methyl acrylate | 1919 | B | | Methylamine solutions | 1235 | C | | (42% or less) | | | Methylamyl acetate | 1233 | (C) | |-------------- |-------------- | Substance | I | II | III | IV |---------|---|---|---|--- | Methylamyl alcohol | 2053 | (C) | | Methyl amyl ketone | 1110 | (C) | | Methyl butenol | (D) | | Methyl tert-butyl ether | 2398 | D | | methyl butyl ketone | D | | Methylbutynol | D | | Methyl butyrate | 1237 | (C) | | Methylcyclohexane | 2296 | (C) | | Methylcyclopentadiene dimer | (B) | | 2-Methyl-6-ethyl aniline | C | | 2-Methyl-5-ethylpyridine | 2300 | (B) | | Methyl formate | 1243 | D | | Methyl heptyl ketone | B | | Methyl isobutyl ketone | 1245 | D | | Methyl methacrylate | 1247 | D | | Methylnaphthalene | A | 0.1 | 0.05 | 2-Methyl-1-1pentene | 2288 | C | | Methyl propyl ketone | D | | 2-Methylpryidine | 2313 | B | | 4-Methylpryidine | 2313 | B | | N-Methyl-2-pyrrolidone | B | | Methyl salicylate | (B) | | alpha-Methylstyrene | 2303 | A | 0.1 | 0.05 | Morpholine | 2054 | D | | Motor fuel anti-knock | 1649 | A | 0.1 | 0.05 | compounds | | | Naphthalene (molten) | 2304 | A | 0.1 | 0.05 | Naphthalene sulphonic | D | | acid-formaldehyde copolymer, | | | sodium salt solution | | | Naphthenic acids | A | 0.1 | 0.05 | Neodecanoic acid | C | | Nitrating acid (mixture of | 1796 | (C) | | sulphuric and nitric acids) | | | Nitric acid (less than 70%) | 2031 | C | | Nitric acid (70% and over) | 2031,| C | | 2032 | | |-------------- |-------------- | Substance | I | II | III | IV |---------|---|---|---|--- | Nitrilotriacetic acid, | D | | trisodium salt solution | | | Nitrobenzene | 1662 | B | | o-Nitrophenol (molten) | 1663 | B | | 1-or 2-Nitropropane | 2608 | D | | Nitropropane (60%) | 1993 | D | | Nitroethane (40%) mixture | | | o-or p-Nitrotoluenes | 1664 | C | | Nonane (all isomers) | 1920 | (C) | | Nonanoic acid (all isomers) | D | | Nonene | B | | Nonyl alcohol (all isomers) | C | | Nonyl methacrylate monomer | (D) | | Nonylphenol | A | 0.1 | 0.05 | Nonyl phenol poly (4-12) | B | | ethoxylates | | | Octane (all isomers) | 1262 | (C) | | Octanoic acid (all isomers) | D | | Octanol (all isomers) | C | | Octene (all isomers) | B | | n-Octyl acetate | D | | Octyl aldehydes | (B) | | Octyl nitrates (all isomers) | A | 0.1 | 0.05 | Olefin mixtures (C - C ) | C | | 5 7 | | | Olefin mixtures (C - C ) | B | | 5 15 | | | alpha-Olefins (C - C ) | B | | 6 18 | | | mixtures | | | Oleic acid | D | | Oleum | 1831 | C | | Palm nut oil fatty acid | (C) | | Palm oil fatty acid | D | | methyl ester | | | Palm stearin | D | | Paraldehyde | 1264 | C | | Pentachloroethane | 1669 | B | | 1, 3-Pentadiene | C | | Pentaethylenehexamine | D | |-------------- |-------------- | Substance | I | II | III | IV |---------|---|---|---|--- | Pentane (all isomers) | 1265 | (C) | | Pentanoic acid | D | | Pentene (all isomers) | C | | Perchloroethylene | 1897 | B | | Phenol | 2312 | B | | 1-Phenyl-1-xylyl ethane | C | | Phosphoric acid | 1805 | D | | Phosphorus, yellow or white | 1381,| A | 0.1 | 0.05 | 2447 | | | Phthalic anhydride (molten) | 2214 | C | | Pinene | 2368 | B | | Polyalkylene glycol butyl | D | | ether | | | Polyethylene polyamines | 2734,| (C) | | 2735 | | | Polyferric sulphate solution | (C) | | Polymethlyene polyphenyl | 2207 | D | | isocyanate | | | Polypropylene glycol | D | | Potassium hydroxide solution | 1814 | C | | n-Propanolamine | C | | beta-Propiolactone | D | | Propionaldehyde | 1275 | D | | Propionic acid | 1848 | D | | Propionic anhydride | 2496 | C | | Propionitrile | 2404 | C | | n-Propyl acetate | 1276 | D | | n-Propylamine | 1277 | C | | n-Propylbenzene | 2364 | (C) | | n-Propyl chloride | B | | Propylene dimer | (C) | | Propylene glycol ethyl ether | (D) | | Propylene glycol methyl ether| (D) | | Propylene glycol monoalkyl | (D) | | ether | | | Propylene oxide | 1280 | D | | Propylene tetramer | 2850 | B | |-------------- |--------------- | Substance | I | II | III | IV |---------|---|---|---|-- | Propylene trimer | 2057 | B | | Pyridine | 1282 | D | | Rosin | B | | Rosin soap | B | | (disproportionated) solution | | | Silicon tetrachloride | D | | Sodium aluminate solution | C | | Sodium borohydride (15% or | C | | less) /Sodium hydroxide solution | | | Sodium carbonate solution | D | | Sodium dichromate solution | C | | (70% or less) | | | Sodium hydrogen sulphite | 2693 | D | | Solution (35% or less) | | | Sodium hydrosulphide/ | B | | Ammonium sulphide solution | | | Sodium hydrosulphide | 2949 | B | | solution (45% or less) | | | Sodium hydroxide solution | 1824 | D | | Sodium hypochlorite solution | 1791 | C | | (15% or less) | | | Sodium nitrite solution | 1500 | B | | Sodium silicate solution | D | | Sodium suphide solution | B | | Sodium sulphite solution | C | | Sodium thiocyanate solution | (B) | | (56% or less) | | | Styrene monomer | 2055 | B | | Sulpholane | D | | Sulphuric acid | 1830 | C | | Sulphuric acid, spent | 1832 | C | | Tall oil (crude and distilled) | B | | Tall oil fatty acid | (C) | | (resin acids less than 20%) | | | Tall oil soap | B | | (dispropotionated) solution | | | Tallow | D | |--------------- |------------------ | Substance | I | II | III | IV |-----------|---|--|---|--- | Tallow fatty acid | (D) | | Tetrachloroethance | 1702 | B | | Tetraethylenepentamine | 2320 | D | | Tetrahydrofuran | 2056 | D | | Tetrahydronaphthalene | C | | 1, 2, 3, 5-Tetramethylbenzene | (C) | | Titanium tetrachloride | 1838 | D | | Toluene | 1294 | C | | Toluenediamine | 1709 | C | | Toluene diisocyanate | 2078 | C | | o-Toluidine | 1708 | C | | Tributyl phosphate | B | | 1, 2, 4-Trichlorobenzene | 2321 | B | | 1, 1, 1-Trichloroethane | 2831 | B | | 1, 1, 2-Trichloroethance | B | | Trichloroethylene | 1710 | B | | 1, 2, 3-Trichloropropane | B | | 1, 1, 2-Trichloro-1, 2, 2-trifluoro- | C | | ethane | | | Tricresyl phosphate | A | 0.1 | 0.05 | (containing less than 1% | | | ortho-isomer) | | | Tricresyl phosphate | 2574*| A 0.1 | 0.05 | | (containing 1% or more | | | ortho-isomer) | | | Triethanolamine | D | | Triethylamine | 1296 | C | | Triethylbenzene | A | 0.1 | 0.05 | Triethylene glycol ethyl ether | (D) | | Triethylene glycol methyl | (D) | | ether | | | Triethylenetetramine | 2259 | D | | Trimethylacetic acid | D | | Trimethylamine | C | | Trimethyl benzenes | B | | (all isomers) | | |------------------ [* UN no. 2574 applies to tricresyl phosphate containing more than 3% ortho-isomer] |----------------- | Substance | I | II | III | IV |----------|---|---|---|--- | Trimethylhexamethylene | 2327 | D | | diamine (2, 2, 4-and 2, 4, 4- | | | isomers) | | | Trimethylhexamethylene | 2328 | B | | diisocyanate (2, 2, 4-and | | | 2, 4, 4-isomers) | | | Trimethylol propane | D | | polyethoxylate | | | 2, 2, 4-Trimethyl-1, 3-pentane- | C | | diol-1-isobutyrate | | | Tripropylene glycol methyl | (D) | | ether | | | Trixylyl phosphate | A | 0.1 | 0.05 | Turpentine | 1299 | B | | Undecanoic acid | (C) | | 1-Undecene | B | | Undecyl alcohol | B | | Urea/Ammonium mono-and | (D) | | di-hydrogen phosphite/ | | | Potassium chloride solution | | | Urea/Ammonium nitrate | D | | solution | | | Urea/Ammonium solution | C | | (containing aqua ammonia) | | | Urea/Ammonium phosphate | D | | solution | | | n-Valeraldehyde | 2058 | D | | Vegetable oil, n.o.s., including: | D | | Castor oil | | | Coconut oil | | | Corn oil | | | Cottonseed oil | | | Groundnut oil | | | Linseed oil | | | Olive oil | | | Palm nut oil | | | Palm oil | | |----------------- |--------------- | Substance | I | II | III | IV |--------|---|---|---|--- | Rape seed oil | | | Rice bran oil | | | Safflower oil | | | Sesame oil | | | Soya bean oil | | | Sunflower oil | | | Tung oil | | | Vinyl acetate | 1301 | C | | Vinyl ethyl ether | 1302 | C | | Vinylidene chloride | 1303 | B | | Vinyl neodecanoate | B | | Vinyltoluene | 2618 | A | 0.1 | 0.05 | White spirit, low (15-20%) | 1300 | (B) | | aromatic | | | Xylenes | 1307 | C | | Xylenol | 2261 | B | |--------------- Appendix III List of other liquid substances |------------------ | Substance UN no.

|------------------ | Acetone 1090 | Acetonitrile 1648 | Alcoholic beverages, n.o.s.

| Alcohols (C and above) | 13 | Aminoethyldiethanolamine/Aminoethylethanolamine solution | 2-Amino-2-hydroxymethyl-1, 3-propanediol solution (40% or less) | tert-Amyl alcohol 1105 | Apple juice | Behenyl alcohol | Benzene triocarboxylic acid, trioctyl ester | n-Butyl alcohol 1120 | sec-Butyl alcohol 1120 | tert-Butyl alcohol 1120 | Butyl stearate | Calcium carbonate slurry | Calcium nitrate/Magnesium nitrate/Potassium chloride solution | Cetyl/Eicosyl methacrylate mixture | Cetyl/Stearyl alcohol | Chlorinated paraffins (C - C ) (with 52% chlorine) | 14 17 | Clay slurry | Coal slurry | Dextrose solution | Diethanolamine | Diethyl ether 1155 | Diethylene glycol | Diethylene glycol butyl ether | Diethylene glycol diethyl ether | Diethylene glycol ethyl ether | Diethylenetriamine pentaacetic acid, pentasodium salt solution | Diheptyl phthalate | Dihexyl phthalae | Diisooctyl phthalate | Dioctyl phthalate |------------------ Substance UN no.

|------------------ | Dipropylene glycol | Dodecane (all isomers) | Dodecylbenzene | Dodecyl methacrylate | Dodecyl/Pentadecyl methacrylate mixture | Drilling brines: | Calcium bromide solution | Calcium chloride solution | Sodium chloride solution | Ethyl alcohol 1170 | Ethylene carbonate | Ethylene glycol butyl ether 2369 | Ethylene glycol tert-butyl ether | Ethylene-vinyl acetate copolymer (emulsion) | Fatty acid (saturated, C and above) | 13 | Glucose solution | Glycerine | Glycerol polyalkoxylate | Glyceryl triacetate | Glycine, sodium salt solution | Hexamethylene glycol | Hexylene glycol | lsobutyl alcohol 1212 | lsopropyl acetate 1220 | lsopropyl alcohol 1219 | Kaolin slurry | Lard | Latex: | Carboxylated styrene-butadiene copolymer | Styrene-butadiene rubber | Lignin sulphonic acid, sodium salt solution | Magnesium chloride solution | Magnesium hydroxide slurry | 3-Methoxy-1-butanol | Methyl acetate 1231 | Methyl alcohol 1230 | Methyl ethyl ketone |------------------ Substance UN no.

|------------------ | 2-Methyl-2-hydroxy-3-butyne | 3-Methyl-3-methoxy butanol | 3-Methyl-3-methoxy butyl acetate | Molasses | Octyl decyl adipate | alpha-Olefins (C - C ) | 13 18 | Olefins (C and above, all isomers) | 13 | n-Paraffine (C - C ) | 10 20 | Paraffin wax | Petrolatum | Polyaluminium chloride solution | Polybutene | Polyethylene glycol dimethyl ether | Polyethylene glycols | Polypropylene glycol dimethyl ether | Polyethylene glycols | Polypropylene glycol methyl ether | Polysiloxane | n-Propyl alcohol | Propylene glycol | Propylene-butylene copolymer | Sodium aluminosilicate slurry | Sodium chlorate solution (50% or less) 2428 | Sorbitol solution | Sulphur (molten) 2448 | Tetraethylene glycol | Tridecane | Tridecanoic acid | Triethylene glycol | Triethylene glycol butyl ether | Triisopropanolamine | Tripropylene glycol | Urea formaldehyde resin solution | Urea solution | Vegetable protein solution (hydrolyzed) | Water |------------------ Appendix IV Cargo Record Book for ships carrying noxious liquidsubstances in bulk FORM OF CARGO RECORD BOOK CARGO RECORD BOOK FOR SHIPS CARRYING NOXIOUS LIQUID SUBSTANCES IN BULK Name of ship ........................................................

Distinctive number or letters ..........................................................

Gross tonnage .......................................................

Period from ...........................to ...........................

Note: Every ship carrying noxious liquid substances in bulk shall be provided with a Cargo Record Book to record relevant cargo/ballast operations.

Name of ship ........................................................

Distinctive number or letters ..........................................................

PLAN VIEW OF CARGO AND SLOP TANKS (to be completed on board) |---------- | Identification | | Capacity | | of the tanks | |-------|----| | | |-------|----| | | |-------|----| | | |-------|----| | | |-------|----| | | |-------|----| | | |-------|----| | | |---------- (Give the capacity of each tank in cubic metres.) Introduction The following pages show a comprehensive list of items of cargo and ballast operations which are, when appropriate, to be recorded in the Cargo Record Book on a tank-to-tank basis in accordance with paragraph 2 of regulation 9 of Annex II of the International Convention for the Prevention of Pollution from Ships, 1973, as modified by the Protocol of 1978 relating thereto, as amended. The items have been grouped into operational sections, each of which is denoted by a letter.

When making entries in the Cargo Record Book, the date, operational code and item number shall be inserted in the appropriate columns and the required particulars shall be recorded chronologically in the blank spaces.

Each completed operation shall be signed for and dated by the officer or officers in charge and, if applicable, by a surveyor authorized by the competent authority of the State in which the ship is unloading. Each completed page shall be countersigned by the master of the ship.

Entries in the Cargo Record Book are required only for operations involving Categories A, B, C and D substances.

List of items to be recorded Entries are required only for operations involving Categories A, B, C and D substances.

A. Loading of cargo 1. Place of loading.

2. Identify tank(s), name of substance(s) and category(ies).

B. Internal transfer of cargo 3. Name and category of cargo(es) transferred.

4. Identity of tanks: .1 from: .2 to: 5. Was(were) tank(s) in 4.1 emptied? 6. If not, quantity remaining in tank(s).

C. Unloading of cargo 7. Place of unloading.

8. Identity of tank(s) unloaded.

9. Was (were) tank(s) emptied? .1 If yes, confirm that the procedure for emptying and stripping has been performed in accordance with the ship's Procedures and Arrangements Manual (i.e.list, trim, stripping temperature).

.2 If not, quantity remaining in tank(s).

10. Does the ship's Procedures and Arrangements Manual require a prewash with subsequent disposal to reception facilities? 11. Failure of pumping and/or stripping system: .1 time and nature of failure; .2 reasons for failure; .3 time when system has been made operational.

D. Mandatory prewash in accordance with the ship's Procedures and Arrangements Manual 12. Identify tank(s), substance(s) and category(ies).

13. Washing method: .1 number of washing machines per tank; .2 duration of wash/washing cycles; .3 hot/cold wash.

14. Prewash slops transferred to: .1 reception facility in unloading port (identify port); .2 reception facility otherwise (identify port).

E. Cleaning of cargo tanks except mandatory prewash (other prewash operations, final wash, ventilation etc.) 15. State time, identify tank(s), substance(s) and category(ies) and state: .1 washing procedure used; .2 cleaning agent(s) (identify agent(s) and quantities); .3 dilution of cargo residues with water (state how much water used (only Category D substances)); .4 ventilation procedure used (state number of fans used, duration of ventilation).

16. Tank washings transferred: .1 into the sea; .2 to reception facility (identify port); .3 to slops collecting tank (identify tank).

F. Discharge into the sea of tank washings 17. Identify tank(s): .1 Were tank washings discharged during cleaning of tank(s)? If so at what rate? .2 Were tank washing(s) discharged from a slops collecting tank? If so, state quantity and rate of discharge.

18. Time pumping commenced and stopped.

19. Ship's speed during discharge.

G. Ballasting of cargo tanks 20. Identity of tank(s) ballasted.

21. Time at start of ballasting.

H. Discharge of ballast water from cargo tanks 22. Identity of tank(s).

23. Discharge of ballast: .1 into the sea; .2 to reception facilities (identify port).

24. Time ballast discharge commenced and stopped.

25. Ship's speed during discharge.

I. Accidental or other exceptional discharge 26. Time of occurrence.

27. Approximate quantity, substance(s) and category (ies).

28. Circumstances of discharge or escape and general remarks.

J. Control by authorized surveyors 29. Identify port.

30. Identify tank(s), substance(s), category(ies) discharged ashore.

31. Have tank(s), pump(s), and piping system(s) been emptied? 32. Has a prewash in accordance with the ship's Procedures and Arrangements Manual been carried out? 33. Have tank washings resulting from the prewash been discharged ashore and is the tank empty? 34. An exemption has been granted from mandatory prewash.

35. Reasons for exemption.

36. Name and Signature of authorized surveyor.

37. Organization, company, government agency for which surveyor works.

K. Additional operational procedures and remarks Name of ship Distinctive number or letters CARGO/BALLAST OPERATIONS |---------------------- | Code | Item | Record of operations/signature of officer in charge/ | | Date | | | (letter)| (number)| name of and signature of authorized surveyor | |---|---|---|--------------| | | | | | | | | | |---|---|---|--------------| | | | | | | | | | |---|---|---|--------------| | | | | | | | | | |---|---|---|--------------| | | | | | | | | | |---------------------- Signature of master Appendix V Form of certificate INTERNATIONAL POLLUTION PREVENTION CERTIFICATE FOR THE CARRIAGE OF NOXIOUS LIQUID SUBSTANCES IN BULK Issued under the provisions of the International Convention for the Prevention of Pollution from Ships, 1973, as modified by the Protocol of 1978 relating thereto, as amended (hereinafter referred to as "the Convention"), under the authority of the Government of (full official designation of the country) by (full official designation of the competent person or organization authorized under the provisions of the Convention) |------------- | Name of | Distinctive | Port of | Gross | | number or | | | ship | letters | registry | tonnage | |-----|-----|---|---| | | | | | | | | | | | | | | | |------------- THIS IS TO CERTIFY: 1. That the ship has been surveyed in accordance with the provisions of regulation 10 of Annex II of the Convention 2. That the survey showed that the structure, equipment, systems, fitting, arrangements and material of the ship and the condition thereof are in all respects satisfactory an d that the ship complies with the application requirements of Annex II of the Convention.

3. That the ship has been provided with a manual in accordance with the standards for procedures and arrangements as called for by regulation 5,5A and 8 of Annex II of the Convention, and that the arrangements and equipment of the ship prescribed in the manual are in all respects satisfactory and comply with the applicable requirements of the said Standards.

4. That the ship is suitable for the carriage in bulk of the following noxious liquid substances, provided that all relevant operational provisions of Annex II of the Convention are observed.

|------------------- | Noxious liquid | Conditions of carriage | | | | substances | (tank numbers etc.) | |--------|----------| | | | | | | | | | | |------------------| | * Continued on additional signed an d dated sheets | |------------------| [* Delete as necessary.] This certificate is valid until subject to surveys in accordance with regulation 10 of Annex II of the Convention Issued at (Place of issue of certificate) 19 (Date of issue) (Signature of duly authorized official issuing the certificate) (Seal or stamp of the issuing authority, as appropriate) ENDORSEMENT FOR ANNUAL AND INTERMEDIATE SURVEYS THIS IS TO CERTIFY that at a survey required by regulation 10 of Annex II of the Convention the ship was found to comply with the relevant provisions of the Convention: Annual survey: Signed (Signature of duly authorized official) Place Date (Seal or stamp of the authority, as appropriate) Annual */Intermediate* survey: Signed (Signature of duly authorized official) Place Date (Seal or stamp of the authority, as appropriate) Annual */Intermediate* survey: Signed (Signature of duly authorized official) Place Date (Seal or stamp of the authority, as appropriate) [* Delete as appropriate.] Annual survey: Signed (Signature of duly authorized official) Place Date (Seal or stamp of the authority, as appropriate) Texts of the Agreed Unified Interpretations of Annex II (Unless specified, regulations referred to are those of Annex II.) 1. Definitions Reg.1.(12) 1.1 Conversion and modification of ships built before 1 July 1986 1.1.1 An oil tanker or a chemical tanker previously not certified to carry safety hazard chemicals but which changes to a service of carrying these cargoes should be considered as having undergone a conversion. Safety hazard cargoes are identified in chapter 6 of the Bulk Chemical Code (BCH Code) or chapter 17 of the International Bulk Chemical Code (IBC Code.) 1.1.2 The last sentence of regulation 1(12) should apply only to modifications made on oil tankers and chemical tankers and the expression "modification" referred thereto should generally be those changes necessary to comply with Annex II and include the fitting of improved stripping systems and underwater discharge arrangements but do not include major structural changes such as those which might be necessary to comply with ship type requirements.

2. Application Reg.2(5) and 2(6) 2.1 Equivalency for gas carriers 2.1.1 With respect to liquefied gas carriers carrying Annex II substances listed in the Gas Carrier Code, equivalency may be permitted under the terms of regulation 2(5) on construction and equipment requirements contained in regulations 5,5A and 13 when a gas carrier meets all the following conditions: .1 hold a Certificate of Fitness in accordance with the appropriate Gas Carrier Code for ships carrying liquefied gases in bulk; .2 hold an International Pollution Prevention Certificate for the Carriage of Noxious Liquid Substances in Bulk (NLS Certificate); .3 be provided with segregated ballast arrangements; .4 be provided with deep well pumps and arrangements which minimize the amount of cargo residue remaining after discharge, to the extent that the Administration is satisfied on the basis of the design that the stripping requirements of regulation 5A (2) (b) or 5A (4) (b), without regard to the limiting date, are met and the cargo residue can be vented to the atmosphere through the approved venting arrangements; .5 be provided with a Procedures and Arrangements Manual approved by the Administration. This manual should ensure that no operational mixing of cargo residues and water will occur and, after venting, no cargo residues will remain and .6 be certified in an NLS Certificate to carry only those Annex II noxious liquid substances listed in the appropriate Gas Carrier Code.

When such equivalency is granted, notification regulated by regulation 2(6) need not be made.

2A. Categorisation of substances Reg.3(4) 2A.1 When a substance which is not included in appendix II or III of MARPOL 73/78 is offered for bulk carriage, the provisional category should be established in accordance with the following procedure: * [* in carrying out the evaluation of substances, it will be necessary to establish minimum carriage requirements not only for Annex II purposes but also for safety purposes. Due regard should, therefore, be given to the "Criteria for Hazard Evaluation of Bulk Chemicals" approved by the MSC at its forty-second session (Annex 3 to the 1985 edition of the BCH Code, also included in the 1986 editions of the BCH and I BC Codes).] .1 The Government of the State Party to MARPOL 73/78 shipping or producing the substance should check MEPC circulars to see whether the substance has been categorized by the Organization, or provisionally assessed by another State Party to MARPOL 73/78; .2 if no information is found in the circulars, the Government of the Party should contact the Organization ** to see if the substance has already been given a provisional assessment by the Organization or by another Government of a Party to MARPOL 73/78. if the latter is the case, the details should be obtained and, if satisfied, the Government of the Party may accept that provisional assessment; [** The enquiry should be addressed to: The Director, MED, IMO, 4 Albert Embankment, London SE1 7SR, United Kingdom; tel.: +44 71 735 7611, telex: 23588 IMOLDNG, telex: +44 71 587 3210; and include enquirer's mailing address, telex and telex numbers. The latter, if available, would facilitate a quick reply.] .3 if there has been no previous provisional assessment, or the Government of the Party is not satisfied with the previous provisional assessment given, the Government of the Party shipping or producing the substance should carry out a provisional assessment in accordance with the attached guidelines; * [* The Guidelines for the provisional assessment of liquid substances offered to be carried in bulk have been superseded by the Guidelines for the provisional assessment of liquids transported in bulk.] .4 the Government of the Party should notify the Government of the State in whose port the cargo will be received and the Government of the flag State of their assessment along with information providing the basis for their pollution and safety hazard assessment, or the provisional assessment registered at the Organization, by the quickest means available; .5 in the event of disagreement, the most severe conditions proposed should prevail; .6 in the absence of an interim or final response to the notification from any of the other Parties involved within 14 days of the despatch, the provisional assessment made by the Government of the Party shipping or producing the substance should be deemed to have been accepted; .7 the Organization should be notified and details provided of the provisional assessment made as required by regulation 3(4) (i.e. with in 90 days, but preferably as soon as possible); .8 the Organization should circulate the information as it is received through an MEPC circular and submit provisional assessments to the BCH Sub-Committee for review. The Organization should also maintain a register of all such substances and their provisional assessments until such time as the substances are formally included in the Annex II lists and the IBC and BCH Codes; and .9 the Organization should forward to GESAMP all such information received, with a view to formal hazard evaluation and subsequent categorization and establishment of minimum carriage requirements by the BCH Sub-Committee, with a view to formal amendment of Annex II of MARPOL 73/78 and the IBC and BCH Codes.

2A.2 In the case that such provisionally assessed substances fall into Category A,B,C or D, amendment sheets to the ship's Certificate of Fitness, or to the NLS Certificate only in cases of Category D substances, and to the Ship's Procedures and Arrangements (P and A) Manual should be issued by the Administration before the ship sails, thus permitting their carriage. This authorization for the carriage of the substance may take the form of telex or equivalent means, which should be kept with the ship's Certificate of Fitness and P and A Manual until the substance is accepted as an amendment to the IBC/BCH Codes. Then the certificate and the P and A Manual should formally be amended.

2A.3 In cases where it is necessary to provisionally assess pollutant-only mixtures, which contain substances for which the Organization has assigned a pollution category or a provisional pollution category and for which the Organization has assigned a ship type or provisional ship-type requirement, the following procedure may be applied in lieu of 2A.1, subparagraphs. 4,.5 and. 6: .1 the mixtures need only be categorized by the Government of the Party shipping or producing the mixture, by the use of the calculation procedure described in section 5 of the Guidelines for the Provisional Assessment of Liquids Transported in Bulk; .2 the mixtures may contain up to 1 percent un-assisted components which could be evaluated by the Government of a Party shipping or producing the mixture; .3 the Government of the Party should notify the Government of the State in whose port the cargo will be received and the Government of the flag State of the assessment; and .4 the Government of the Party may authorize the manufacturer to carry out the assignment (n.o.s number, the appropriate shipping name, viscosity and melting point) on its behalf. In this case the obligation to inform flag States and receiving countries of the performed assignment falls on the authorized manufacturer. The manufacturer should also inform the authorizing Government of the assignment performed along with details of the assessment. The manufacturer should inform IMO if so requested by the Government of the shipping or producing country. Upon request, the manufacturer should provide the Government of the flag State or receiving State with full details of the mixture. Notification of the assignment by the manufacturer should be accompanied by the authorization letter indicating that the manufacturer acts under instruction and on behalf of the Government of the Party.

2A.4 Notwithstanding 2A.2, if a ship is certified fit to carry n.o.s. (not otherwise specified) substances of the provisionally assessed category and ship type, no amendment need be made to the ship's Certificate of Fitness or the ship's P and A Manual.

3. Discharge or residue Reg.5 3.1 En route 3.1.1 The term "en route" is taken to mean that the ship is under way at sea on a course, or courses, which so far as practicable for navigational purposes will cause any discharge to be spread over as great an area of the sea as is reasonably practicable.

4. Pumping, piping and unloading arrangements Reg.5A 4.1, (6) (b) (iv), and (7) (e) Appropriate action in case of exemption 4.1.1 With regard to the term "appropriate action, if any", any Party to the Convention that has an objection to the particulars of an exemption submitted by another Party should communicate this objection to the Organization and to the Party which issued the exemption within one year after the Organization circulates the particulars of the exemption to the Parties.

5. Reception facilities Reg.7 (1) (b) 5.1 Reception facilities in repair ports 5.1.1 This regulation is taken to mean that ship repair ports undertaking repairs to chemical tankers should have facilities adequate for the reception of residues and mixtures containing noxious liquid substances as would remain for disposal from ships carrying them as are result of the application of this Annex.

Reg.8 (5) (a) (i), and (7) (a) (i), 5A, Measures of control 5A.1 The wording "substance unloaded is identified in the standards developed by the Organization as resulting in a residue quantity exceeding the maximum quantity which may be discharged into the sea" of subparagraphs 5 (a) (i) and 7 (a) (i) of regulation 8 refers to high-viscosity or solidifying substances as defined in paragraphs 1.3.7 and 1.3.9 of the Standards for Procedures and Arrangements.

6. Survey and certification Reg.10 (1)(c) and (d), 6.1 Intermediate and annual surveys for ships not required to hold NLS Certificate 6.1.1 The applicability of regulation 10 (1) (c) and (d) and/or corresponding requirements of the IBC and BCH Codes under regulation 12A to ships which are not required to hold an International Pollution Prevention Certificate for the Carriage of Noxious Liquid Substances in Bulk by virtue of regulation 11 should be determined by the Administration.

6A.1 Requirements for minimizing accidental pollution Reg.13(4) 6A.1.1 Ships other than chemical tankers For the purpose of regulation 13(4) of Annex II of MARPOL 73/78, the Organization has developed guidelines for offshore support vessels and ships engaged in dumping at sea. For the purpose of that regulation, the BCH and the IBC Codes, as applicable to chemical tankers, represent the appropriate guidelines based on which Administrations should establish measures for ships other than chemical tankers, offshore support vessels and dumping vessels carrying Category A, B or C noxious liquid substances in bulk.

7. Oil-like substances Reg.14 7.1 List of oil-like substances Category C substances Category D substances Aviation alkylates Alkyl (C9-C17) benzenes Cycloheptane Diisopropyl naphthalene Cyclohexane Dodecane (all isomers) Cyclopentane p-Cymene Diethylbenzene Dipentene Ethylbenzene Ethylcyclohexane Heptene (all isomers) Hexane (all isomers) Hexene (all isomers) Isopropyl cyclohexane Methylcyclohexane 2-Methyl-1-pentene Nonane (all isomers) Octane (all isomers) Olefin mixtures (C5-C7) Pentane (all isomers) Pentene (all isomers) 1-Phenyl-1-xylylethane Propylene dimer Tetrahydronaphthalene Toluene Xylenes For each of the above substances, compliance with the oil-like substance criterion 7.2.1.4 given below has to be demonstrated for the particular oil content meter installed.

7.2 Selection criteria 7.2.1 The following criteria define an oil-like Category C or D noxious liquid substance: .1 the substance's mass density (specific gravity) is less than 1.0 at 20 ¡æ; .2 the substance's solubility in seawater at 20 ¡æ is less than 0.1 per cent; .3 the substance is a hydrocarbon; .4 the substance can be monitored by an oil content meter required by regulation 15 of Annex I of MARPOL 73/78; * [* In approving an oil discharge monitoring and control system for the purpose of this regulation, the Administration should ensure through tests that the system can monitor concentrations of each oil-like substance in conformity with the Recommendation on International Performance Specifications for Oily-Water Separating Equipment and Oil Content Meters adopted by the Organization by resolution A. 393 (X) or the Revised Guidelines and Specifications for Oil Discharge Monitoring and Control Systems for Oil Tankers, resolution A.586 (14). If it is necessary to readjust the monitor when changing from oil products to oil-like noxious substances, information on the readjustment should be provided and special operating procedures ensuring that discharges of oil-like noxious substances are measured accurately should be approved by the Administration. When the oil content meter is readjusted an entry should be made in the Oil Record Book.] .5 in the case of Category C substances, the ship type requirement, as specified by the Bulk Chemical or International Bulk Chemical Codes, is type 3; and .6 the substance is not regulated by the Bulk Chemical or International Bulk Chemical Codes for safety purposes as indicated in chapters VI and 17 of the Codes respectively.

Reg.14 (c) 7.3 Damage stability calculation 7.3.1 A new ship of 150 metres or more in length under Annex 1 should be considered to comply with the requirements of regulation 14(c) if compliance with regulation 25 of Annex 1 has been demonstrated.

Reg.14(d) 7.4 Applicability of the waiver under regulation 15(5) of Annex 1 of MARPOL 74/78 to oil tankers carrying oil-like Annex II substances 7.4.1 Since regulation 14 of Annex II applies to oil tankers, as defined in Annex I, which are allowed to carry oil-like substances and discharge these under the provisions of Annex I, any waiver granted to such oil tankers in respect of the requirement to be fitted with an oil discharge monitoring and control system encompasses the requirements contained in regulation 14(d) of Annex II. It should be noted, however, that in considering the issuance of a waiver under the provisions of Annex I, an Administration should determine that adequate reception facilities are available to receive the residues and mixtures at loading ports or terminals at which the tanker calls and that the facilities are also suitable for the treatment and ultimate disposal of the oil-like substances received.

Annex III of MARPOL 73/78: Regulations for the Prevention of Pol-lution by Harmful Substances Carried by Sea in Packaged Forms, or inFreight Containers, Portable Tanks or Road and Rail Tank Wagons
Regulation 1 Application (1) Unless expressly provided otherwise, the regulations of this Annex apply to all ships carrying harmful substances in packaged forms, or in freight containers, portable tanks or road and rail tank wagons.

(2) Such carriage of harmful substances is prohibited, except in accordance with the provisions of this Annex.

(3) To supplement the provisions of this Annex, the Government of each Party to the Convention shall issue, or cause to be issued, detailed requirements on packaging, marking, labelling, documentation, stowage, quantity limitations, exceptions and notification for preventing or minimizing pollution of the marine environment by harmful substances.

(4) For the purposes of this Annex, empty receptacles, freight containers, portable tanks, and road and rail tank wagons which have been used previously for the carriage of harmful substances shall themselves be treated as harmful substances unless adequate precautions have been taken to ensure that they contain no residue that is hazardous to the marine environment.

Regulation 2 Packaging Packaging, freight containers, portable tanks and road and rail tank wagons shall be adequate to minimize the hazard to the marine environment having regard to their specific contents.

Regulation 3 Marking and labelling Packages, whether shipped individually or in units or in freight containers, freight containers, portable tanks or road and rail tank wagons containing a harmful substance, shall be durably marked with the correct technical name (trade names shall not be used as the correct technical name) and further marked with a distinctive label or stencil of label, indicating that the contents are harmful. Such identification shall be supplemented where possible by any other means, for example by the use of the United Nations number.

Regulation 4 Documentation (1) In all documents relating to the carriage of harmful substances by sea where such substances are named, the correct technical name of the substances shall be used (trade names shall not be used).

(2) The shipping documents supplied by the shipper shall include a certificate or declaration that the shipment offered for carriage is properly packed, marked and labelled, and in proper condition for carriage to minimize the hazard to the marine environment.

(3) Each ship carrying harmful substances shall have a special list or manifest setting forth the harmful substances on board and the location thereof. A detailed stowage plan which sets out the location of all harmful substances on board may be used in place of such special list or manifest Copies of such documents shall also be retained on shore by the owner of the ship or his representative until the harmful substances are unloaded.

(4) In a case where the ship carries a special list or manifest or a detailed stowage plan, required for the carriage of dangerous goods by the International Convention for the Safety of Life at Sea in force, the documents required for the purpose of this Annex may be combined with those for dangerous goods. Where documents are combined, a clear distinction shall be made between dangerous goods and other harmful substances.

Regulation 5 Stowage Harmful substances shall be both properly stowed and secured so as to minimize the hazards to the marine environment without impairing the safety of the ship and persons on board.

Regulation 6 Quantity limitations Certain harmful substances which are very hazardous to the marine environment may, for sound scientific and technical reasons, need to be prohibited for carriage or be limited as to the quantity which may be carried aboard any one ship. In limiting the quantity due consideration shall be given to size, construction and equipment of the ship as well as the packaging and the inherent nature of the substance.

Regulation 7 Exceptions (1) Discharge by jettisoning of harmful substances carried in packaged forms, freight containers, portable tanks, or road and rail tank wagons shall be prohibited, except where necessary for the purpose of securing the safety of the ship or saving life at sea.

(2) Subject to the provisions of the present Convention, appropriate measures based on the physical, chemical and biological properties of harmful substances shall be taken to regulate the washing of leakages overboard, provided that compliance with such measures would not impair the safety of the ship and persons on board.

Regulation 8 Notification With respect to certain harmful substances, as may be designated by the Government of a Party to the Convention, the master or owner of the ship or his representative shall notify the appropriate port authority of the intent to load or unload such substances at least 24 hours prior to such action.

ANNEX III Draft revised Annex III of MARPOL 73/78: Regulations forthe Prevention of Pollution by Harmful Substances Carried by Sea inPackaged Form Draft revised Annex III of MARPOL 73/78 Regulations for the Prevention of Pollution by Harmful Substances Carried by Sea in Packaged Form Note: Annex III of MARPOL 73/78 enters into force on 1 July 1992. The Marine Environment Protection Committee agreed to adopt this revised Annex III formally in October 1992.

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